Recycling Spent Fluorescent Lamp Glass Waste in Calcium Aluminate Cement: Effects on Hydration and Mechanical Performance
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Date
2025Unesco Subject/s
3305.33 Resistencia de Estructuras
3308 Ingeniería y Tecnología del Medio Ambiente
3308.07 Eliminación de Residuos
Abstract
Featured Application: This study presents a novel application of spent fluorescent lamp glass (SFLG) waste as a partial replacement for calcium aluminate cement (CAC), offering a sustainable solution for hazardous waste reuse and reducing CAC’s environmental impact. Mortars with 25–50 wt.% SFLG showed enhanced long-term strength due to strätlingite formation, which limited harmful phase conversion. Residual mercury in SFLG was safely encapsulated, ensuring environmentally safe waste management. Calcium aluminate cement (CAC) offers rapid strength development, chemical durability in harsh environments, and high-temperature resistance, but its long-term performance may be compromised by the conversion of metastable hexagonal hydrates into stable cubic phases. Concurrently, recycling spent fluorescent lamp glass (SFLG) is limited because of its residual mercury content. This study investigates the use of manually (MAN) and mechanically (MEC) processed SFLG as partial CAC replacements (up to 50 wt.%). Both SFLG types had irregular morphologies with mean particle sizes of ~20 µm and mercury concentrations of 3140 ± 61 ppb (MAN) and 2133 ± 119 ppb (MEC). Moreover, the addition of SFLG reduced the initial and final setting times, whilst MEC waste notably extended the plastic state duration from 20 min (reference) to 69 min (50 wt.% MEC). Furthermore, strength development was accelerated, with SFLG/CAC mortars reaching peak strengths at 7–10 days versus 28 days as in the CAC reference. CAC and 15 wt.% SFLG mortars showed strength loss over time by reason of their phase conversion, whereas mortars with 25–50 wt.% SFLG experienced significant long-term strength gains, reaching ~60 MPa (25 wt.%) and ~45 MPa (35 wt.%), respectively, after 365 days, with strength activity indexes (SAI) near 90% and 70%, respectively. These improvements are attributed to the formation of strätlingite (C2ASH8), which stabilized hexagonal CAH10 and mitigated conversion to cubic katoite (C3AH6). Mercury leaching remained below 0.01 mg/kg dry matter for all mixes and curing ages, classifying the mortars as non-hazardous and inert under Spanish Royal Decree 646/2020. The results suggest that SFLG can be safely reused as a sustainable admixture in CAC systems, enhancing long-term mechanical performance while minimizing environmental impact. © 2025 by the authors.
Featured Application: This study presents a novel application of spent fluorescent lamp glass (SFLG) waste as a partial replacement for calcium aluminate cement (CAC), offering a sustainable solution for hazardous waste reuse and reducing CAC’s environmental impact. Mortars with 25–50 wt.% SFLG showed enhanced long-term strength due to strätlingite formation, which limited harmful phase conversion. Residual mercury in SFLG was safely encapsulated, ensuring environmentally safe waste management. Calcium aluminate cement (CAC) offers rapid strength development, chemical durability in harsh environments, and high-temperature resistance, but its long-term performance may be compromised by the conversion of metastable hexagonal hydrates into stable cubic phases. Concurrently, recycling spent fluorescent lamp glass (SFLG) is limited because of its residual mercury content. This study investigates the use of manually (MAN) and mechanically (MEC) processed SFLG as partial CAC replacements (up to 50 wt.%). Both SFLG types had irregular morphologies with mean particle sizes of ~20 µm and mercury concentrations of 3140 ± 61 ppb (MAN) and 2133 ± 119 ppb (MEC). Moreover, the addition of SFLG reduced the initial and final setting times, whilst MEC waste notably extended the plastic state duration from 20 min (reference) to 69 min (50 wt.% MEC). Furthermore, strength development was accelerated, with SFLG/CAC mortars reaching peak strengths at 7–10 days versus 28 days as in the CAC reference. CAC and 15 wt.% SFLG mortars showed strength loss over time by reason of their phase conversion, whereas mortars with 25–50 wt.% SFLG experienced significant long-term strength gains, reaching ~60 MPa (25 wt.%) and ~45 MPa (35 wt.%), respectively, after 365 days, with strength activity indexes (SAI) near 90% and 70%, respectively. These improvements are attributed to the formation of strätlingite (C2ASH8), which stabilized hexagonal CAH10 and mitigated conversion to cubic katoite (C3AH6). Mercury leaching remained below 0.01 mg/kg dry matter for all mixes and curing ages, classifying the mortars as non-hazardous and inert under Spanish Royal Decree 646/2020. The results suggest that SFLG can be safely reused as a sustainable admixture in CAC systems, enhancing long-term mechanical performance while minimizing environmental impact. © 2025 by the authors.
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